If you have enabled Self Service Password reset, all users should be prompted to enroll on login. You could also proactively redirect users to https://passwordreset.microsoftonline.com/ or http://aka.ms/ssprsetup

Look at this blogpost for that user experience: Self Service Password Reset User Registration (Same as for MFA registration).

Here is how you get the report for users who signed up for Self Service Password Reset

azure-active-directory-listing-in-azure-management-portal

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Azure AD Report Catalog
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Activity Logs in Azure AD
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Latest activity for SSPR
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Download reports in CSV
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The Report in CSV opened in Excel